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Creators/Authors contains: "Galiano, Layla A"

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  1. ; ; ; ; ; ; ; ; ; ; et al (, Chemical Communications)
    ortho-Nitrosocumene (o-NC) exhibits dynamic N,N bonding, interchanging monomer and E/Z-azodioxide dimer structures, the extent of which depends on the environment. As a solid, o-NC is a Z-dimer; in organic solvent, the monomer is favored; and in water, dimers are favored. A supramolecular assembly of o-NC is observed as a separate species by NMR in water, shown to be a novel nanometer-sized aggregate containing B2000 molecules. 
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    Free, publicly-accessible full text available November 21, 2025